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1.
J Hazard Mater ; 471: 134351, 2024 Apr 19.
Artigo em Inglês | MEDLINE | ID: mdl-38653136

RESUMO

Macrophyte rhizospheric dissolved organic matter (ROM) served as widespread abiotic components in aquatic ecosystems, and its effects on antibiotic residues and antibiotic resistance genes (ARGs) could not be ignored. However, specific influencing mechanisms for ROM on the fate of antibiotic residues and expression of ARGs still remained unclear. Herein, laboratory hydroponic experiments for water lettuce (Pistia stratiotes) were carried out to explore mutual interactions among ROM, sulfamethoxazole (SMX), bacterial community, and ARGs expression. Results showed ROM directly affect SMX concentrations through the binding process, while CO and N-H groups were main binding sites for ROM. Dynamic changes of ROM molecular composition diversified the DOM pool due to microbe-mediated oxidoreduction, with enrichment of heteroatoms (N, S, P) and decreased aromaticity. Microbial community analysis showed SMX pressure significantly stimulated the succession of bacterial structure in both bulk water and rhizospheric biofilms. Furthermore, network analysis further confirmed ROM bio-labile compositions as energy sources and electron shuttles directly influenced microbial structure, thereby facilitating proliferation of antibiotic resistant bacteria (Methylotenera, Sphingobium, Az spirillum) and ARGs (sul1, sul2, intl1). This investigation will provide scientific supports for the control of antibiotic residues and corresponding ARGs in aquatic ecosystems.

2.
Environ Geochem Health ; 46(5): 153, 2024 Apr 08.
Artigo em Inglês | MEDLINE | ID: mdl-38587707

RESUMO

The environmental fate and risks of ciprofloxacin (CIP) in the subsurface have raised intensive concerns. Herein, the transport behaviors of CIP in both saturated quartz sand and sand/multi-walled carbon nanotubes (MWCNTs) mixtures under different solution ionic strength of the solution and coexisting cation types were investigated. Batch adsorption experiments highlighted growing adsorptive capacity for CIP with the increasing content of MWCNTs in the MWCNTs-quartz sand mixtures (from 0.5% to 1.5%, w/w). Breakthrough curves (BTCs) of CIP in the MWCNTs-quartz sand mixtures were well fitted by the two-site chemical nonequilibrium model (R2 > 0.833). The estimated retardation factors for CIP increased from 9.68 to 282 with growing content of MWCNTs in the sand column, suggesting the presence of MWCNTs significantly inhibited the transport of CIP in saturated porous media. Moreover, the values of retardation factors are negatively correlated with the ionic strength and higher ionic strength could facilitate the transport of CIP in the saturated porous media. Compared with monovalent cations (Na+), the presence of divalent cations (Ca2+) significantly facilitated the transport of CIP in the columns due to the complexation between CIP and Ca2+ as well as deposition of MWCNTs aggregates on the sand surface. Results regarding CIP retention in columns indicated that MWCNTs could enhance the accumulation of CIP in the layers close to the influent of sand columns, while they could hinder upward transport of CIP to the effluent. This study improves our understanding for transport behaviors and environmental risk assessments of CIP in the saturated porous media with MWCNTs.


Assuntos
Nanotubos de Carbono , Porosidade , Quartzo , Areia , Cátions , Ciprofloxacina , Concentração Osmolar
3.
Environ Sci Pollut Res Int ; 31(8): 11543-11558, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38212564

RESUMO

Microplastics (MPs) have attracted much attention in recent years, due to the difficulty of degradation and threats to ecological systems and humans. Based on the analysis of 1429 articles on MPs in soil, we found that we know little about the behavior and fate of manure-born MPs from the livestock and poultry production systems to agriculture soils. This review summarizes the analytical methods for sampling, separation, and identification and the occurrence of MPs in livestock and poultry manure, mainly based on 7 surveys related to manure-born MPs. Then, the sources, fate, and environmental risks of MPs in livestock and poultry manure are discussed. MPs, heavy metals, pathogens, antibiotic resistance genes, and persistent organic pollutants are common pollutants in livestock and poultry manure. Worse, manure-born MPs will become smaller, rougher, and more numerous and could easily form more toxic compound pollution after complicated processes of manure treatment, which seriously threatens agricultural soil safety. Finally, an outlook is offered for future research. We hope this article to attract attention to the risks of MPs in livestock and poultry manure and provide a reference for future research.


Assuntos
Aves Domésticas , Solo , Humanos , Animais , Microplásticos , Plásticos , Gado , Esterco , Agricultura
4.
Sci Total Environ ; 869: 161855, 2023 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-36708845

RESUMO

As an emerging environmental contaminant, the widespread of antibiotic resistance has caused a series of environmental issues and human health concerns. A load of antibiotic residues induced by agricultural practices have exerted selective pressure to bacterial communities in the soil-plant system, which facilitated the occurrence and dissemination of antibiotic resistance genes (ARGs) through horizontal gene transfer. As a result, the enrichment of ARGs within crops at harvest under the influence of food ingestion could lead to critical concerns of public health. In this review, the prevalence and dissemination of antibiotic resistance in the soil-plant system are highlighted. Moreover, different underlying mechanisms and detection methods for ARGs transfer between the soil environment and plant compartments are summarized and discussed. On the other hand, a wide range of influencing factors for the transfer and distribution of antibiotic resistance within the soil-plant system are also presented and discussed. In response to exposure of antibiotic residues and resistomes, corresponding hazard identification assessments have been summarized, which could provide beneficial guides of the toxicological tolerance for the general population. Finally, further research priorities for detection and management ARGs spread are also suggested.


Assuntos
Genes Bacterianos , Solo , Humanos , Solo/química , Antibacterianos/farmacologia , Bactérias/genética , Resistência Microbiana a Medicamentos/genética , Microbiologia do Solo
5.
Chemosphere ; 312(Pt 2): 137199, 2023 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-36372338

RESUMO

Wastewater treatment plants (WWTPs) are an important source of microplastics (MPs) entering the aquatic environment. As environmental awareness increases, WWTPs are gradually using constructed wetlands (CWs) in the depth treatment stage. There were few studies related to MPs removal efficiency of CWs, especially in multi-stage and multi-combinations CWs. Therefore, we studied MPs characteristics and removal in a typical CWs WWTP in Changsha, comparing the MPs removal efficiencies of different processes in a WWTP, focusing on the MPs abundance variation in different stages CWs. Result showed that the MPs removal efficiency of Phase Ⅰ was 87.72% and that of Phase II was 80.65%. Approximate estimates showed that the daily discharge of MPs reached 7.20 * 108 items. The MPs removal efficiency of vertical flow CWs was 25.71%. The MPs removal efficiencies of secondary and tertiary horizontal subsurface flow CWs (HSSFCWs) were 32.00% and 21.43%. The MPs removal efficiencies of secondary and tertiary surface flow CWs were 23.53% and 12.50%. The MPs removal efficiencies of three bio-ponds were -23.08%, -12.90%, and -27.27%. Combined system of bio-pond + CWs reduced the MPs removal efficiency. The most dominant shape of MPs in wastewater was fibers. The most common MPs were polyethylene and polystyrene. The primary treatment in the Changsha WWTP had the highest MPs removal efficiency. Results of this investigation showed the multi-combination and multi-stage CWs WWTP can remove most of MPs in influent, which greatly reduced the amount of MPs discharged into the aquatic environment through WWTP and provided data for analyzing the distribution of MPs in the aquatic environment.


Assuntos
Poluentes Químicos da Água , Purificação da Água , Microplásticos , Áreas Alagadas , Plásticos , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/análise , Águas Residuárias/análise
6.
J Colloid Interface Sci ; 629(Pt A): 685-696, 2023 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-36095900

RESUMO

Recently, carbon materials have attracted much attention in activating persulfate (PS) for the removal of organic pollutants. Seeking a greener, lower-cost, and higher-performance carbon material has become an important aspect of research. In this study, candle soot was innovatively used as a nanocarbon material, and its performance for PS activation was improved by simple ammonium ferric citrate modification. The optimal catalytic performance was achieved using 0.15 g/L modified candle soot (AS) and only 0.1 mM PS, with sulfamethoxazole (SMX) removal efficiency up to 95.5% within 120 min. Quenching tests, together with electron paramagnetic resonance measurements, showed that O2- and 1O2 were the main reactive species for SMX degradation. Meanwhile, electron transfer pathway was also occurred. Various characterization results showed that graphitic N and carbonyl group were the main active sites for PS activation. Moreover, AS/PS system exhibited high catalytic activity and stability for SMX degradation over a wide initial pH range (3∼9), or even in the presence of Cl-, H2PO4- and NO3-. This work not only taps the potential of candle soot as an environmental functional material, but also showcases the roadmap for the discovery, design, and resource utilization of other waste carbon materials in wastewater treatment.


Assuntos
Compostos de Amônio , Poluentes Químicos da Água , Sulfametoxazol/química , Nitrogênio , Fuligem , Poluentes Químicos da Água/química , Carbono , Oxirredução
7.
Bioresour Technol ; 370: 128497, 2023 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-36535618

RESUMO

Electrolytic manganese residue poses potentially threats to the environment and therefore needs eco-friendly treatment. Composting has been reported to effectively passivate heavy metals and alleviate their ecotoxicity. Observation of the Mn concentration during composting indicated that the mobility of Mn was significantly reduced, with the easily extraction fraction (acid extractable and easily reduction fraction) of Mn in the control pile (pile 1 without Phanerochaete chrysosporium inoculation) and treat pile (pile 2 with Phanerochaete chrysosporium inoculation) decreasing by 17% and 29%, respectively. The inoculation of Phanerochaete chrysosporium prompted the passivation of manganese, prolonged the thermophilic period, and enriched the microbial community structure, which was attributed to the rapid growth and reproduction of thermophilic bacteria. Moreover, Phanerochaete chrysosporium inoculation promoted the effect of pH on the stabilization of Mn, but the opposite contribution of organic matter. This study would provide a new perspective for remediating EMR contaminated soil via composting.


Assuntos
Compostagem , Microbiota , Phanerochaete , Manganês , Solo/química
8.
Ecotoxicol Environ Saf ; 243: 113958, 2022 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-35987081

RESUMO

Although the influence of microplastics (MPs) in different soil environments has been investigated, their effects on the physiochemical properties and chemical speciation of heavy metals in yellow-brown soil remains unknown. This study aimed to determine the effects of various concentrations of linear low-density polyethylene (LLDPE), polyamide (PA), polyurethane (PU), polystyrene (PS), and low-density polyethylene (LDPE) MPs on the yellow-brown soil environment and chemical speciation of the heavy metals cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn). MPs influenced the physicochemical properties and chemical speciation of heavy metals in yellow-brown soil. The physicochemical properties of yellow-brown soil can be altered by changing the concentrations of LDPE MP. The relationship between changes in field capacity (FC) and LDPE concentrations was approximately linear. The physiochemical properties of yellow-brown soil containing added PA, PU, and LDPE MPs were substantially improved (control vs. MPs): FC, 39 % vs. 42.50 % for PU, cation exchange capacity (CEC) 45.77, 56.65, and 57.44 cmol.kg-1 for PA, PU, and LDPE respectively, and organic matter (OM) content, 40.16 vs. 51.68 g.kg-1 for PA. The LLDPE and PU MPs also simultaneously affected the chemical speciation of heavy metals in yellow-brown soil. The LLDPE MPs increased the acid-soluble (45.17-54.67 % (Cd-F1), 7.24-11.30 % (Cu-F1), 4.20-7.23 % (Pb-F1), 21.21-31.47 % (Zn-F1)) and reducible (24.02-29.41 % (Cd-F2), 25.69-34.95 % (Cu-F2), 74.29-81.07 % (Pb-F2), 28.77-34.19 % (Zn-F2)) fractions of heavy metals, which increased their bioavailability. However, PU MPs reduced the ecological risk of heavy metals in yellow-brown soil by increasing the content of the residual fraction (26.11-40.21 % (Cd-F4), 47.63-59.67 % (Cu-F4), 17.25-26.76 % (Pb-F4), 32.63-50.46 % (Zn-F4)). Changes in the properties of yellow-brown soil and the impact of MPs on heavy metals, might change the chemical speciation of heavy metals. The impact of MPs on heavy metals in yellow-brown soil requires further investigation.


Assuntos
Metais Pesados , Poluentes do Solo , Cádmio , Chumbo , Metais Pesados/análise , Microplásticos , Plásticos , Polietileno , Solo/química , Poluentes do Solo/análise , Zinco
9.
J Hazard Mater ; 438: 129515, 2022 09 15.
Artigo em Inglês | MEDLINE | ID: mdl-35816806

RESUMO

Plastics enter the environment and break up into microplastics (MPs) and even nanoplastics (NPs) by biotic and abiotic weathering. These small particles are widely distributed in the environmental media and extremely mobile and reactive, easily suspending in the air, infiltrating into the soil, and interacting with biota. Current research on MPs/NPs is either in the abiotic or biotic compartments, with little attention paid to the fact that the biosphere as a whole. To better understand the complex and continuous movement of plastics from biological to planetary scales, this review firstly discusses the transport processes and drivers of microplastics in the macroscopic compartment. We then summarize insightfully the uptake pathways of MPs/NPs by different species in the ecological compartment and analyze the internalization mechanisms of NPs in the organism. Finally, we highlight the bioaccumulation potential, biomagnification effects and trophic transfer of MPs/NPs in the food chain. This work is expected to provide a meaningful theoretical body of knowledge for understanding the biogeochemical cycles of plastics.


Assuntos
Microplásticos , Poluentes Químicos da Água , Bioacumulação , Cadeia Alimentar , Plásticos/metabolismo , Poluentes Químicos da Água/análise
10.
Sci Total Environ ; 840: 156355, 2022 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-35654189

RESUMO

Composting, as a conventional solid waste treatment method, plays an essential role in carbon and nitrogen conservation, thereby reducing the loss of nutrients and energy. However, some carbon- and nitrogen-containing gases are inevitably released during the process of composting due to the different operating conditions, resulting in carbon and nitrogen losses. To overcome this obstacle, many researchers have been trying to optimize the adjustment parameters and add some amendments (i.e., pHysical amendments, chemical amendments and microbial amendments) to reduce the losses and enhance carbon and nitrogen conservation. However, investigation regarding mechanisms for the conservation of carbon and nitrogen are limited. Therefore, this review summarizes the studies on physical amendments, chemical amendments and microbial amendments and proposes underlying mechanisms for the enhancement of carbon and nitrogen conservation: adsorption or conversion, and also evaluates their contribution to the mitigation of the greenhouse effect, providing a theoretical basis for subsequent composting-related researchers to better improve carbon and nitrogen conservation measures. This paper also suggests that: assessing the contribution of composting as a process to global greenhouse gas mitigation requires a complete life cycle evaluation of composting. The current lack of compost clinker impact on carbon and nitrogen sequestration capacity of the application site needs to be explored by more research workers.


Assuntos
Compostagem , Carbono , Compostagem/métodos , Gases , Efeito Estufa , Humanos , Esterco , Nitrogênio/análise , Solo
11.
Chemosphere ; 303(Pt 1): 134729, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35525445

RESUMO

Microplastics, as emerging contaminants, have attracted widespread attention for their increasing detection frequency in aquatic environment. It has been reported that microplastics may co-presence with heavy metals in water, which might have impact on heavy metals removal in water. Furthermore, the effects of microplastics on the co-remediation efficiency of plants with engineered nanomaterials are ambiguous. To this end, this study was dedicated to unveil the intrinsic effects of polystyrene microplastics (PSMPs) on the cadmium (Cd) removal efficiency by co-remediation of ryegrass (Lolium perenne L.) and three engineered nanomaterials, respectively were nano-zerovalent iron (nZVI), carboxymethylcellulose-modified-nZVI (C-nZVI) and sulfidated nZVI (S-nZVI). Significant changes were observed in Cd content, plant biomass, chlorophyll b and antioxidant enzymes. It was surprising to find that with the treatment of nZVI or C-nZVI, polystyrene microplastics would enter plants roots, and these plants were found to contain more Cd among all series. Accordingly, four possible mechanisms were proposed to explain why plants that observed the internalization of PSMPs contained more Cd. This work reveals the impact of coexisting microplastics in water on Cd remediation efficiency and provides new insights into the entry of polystyrene microplastics into plant roots.


Assuntos
Lolium , Metais Pesados , Cádmio/farmacologia , Ferro/farmacologia , Metais Pesados/farmacologia , Microplásticos , Plásticos/farmacologia , Poliestirenos/farmacologia , Água/farmacologia
12.
Sci Total Environ ; 812: 151487, 2022 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-34742990

RESUMO

The effect of microplastics on soil ecosystem is a hot topic in recent years. It is increasingly recognized that soil is also an important sink for microplastics in addition to the aquatic environment. This review aims to discuss the direct and indirect effects of microplastics on the soil-plant system, focusing on the effects of microplastics on soil aggregates and soil nutrient cycling as well as the combined effects of microplastics and other pollutants on soil-plant systems. Microplastics have been shown to affect the rooting ability of plants by altering soil bulk density and water-holding capacity, as well as reducing photosynthetic rate by directly interfering with the balance of plant chlorophyll a/chlorophyll b ratios. In addition, microplastics affect the stability of aggregates by interfering with abiotic factors (e.g., sesquioxide and exchangeable cations) or biotic factors (e.g., soil organic matter and organism activities in the soil). Moreover, microplastics may affect soil nutrient cycling by altering the dominant bacteria phyla in the soil or genes and enzymes associated with the carbon, nitrogen, and phosphorus cycle. When microplastics and other pollutants have combined effects on plants, microplastics attached onto the root surface physically hamper the contact of the pollutants with the roots but are more likely to exacerbate the damage of pollutants to plants. Different types, sizes and concentrations of microplastics have different effects on the soil-plant system. Microplastics with similar shape and size to soil particles have less significant effects, while microfibers, small-sized microplastics and biodegradable plastic particles have more significant effects. Finally, this review also provides an outlook for future research.


Assuntos
Microplásticos , Solo , Clorofila A , Ecossistema , Plásticos
13.
Sci Total Environ ; 811: 152352, 2022 Mar 10.
Artigo em Inglês | MEDLINE | ID: mdl-34915001

RESUMO

Wastewater treatment plants (WWTPs) are important pathways that discharged microplastics into the natural environment, but few relevant research has been conducted in rural areas, especially with horizontal subsurface flow constructed wetlands (HSSFCWs). This study systematically investigates the removal efficiency and characteristics of microplastics in two rural WWTPs with HSSFCW in Changsha city of China and compared the microplastic pollution data of urban and rural WWTPs, to provide some advice for improving the microplastics removal efficiencies in rural WWTPs. 3 L wastewater were collected at each sampling point. Then microplastics in wastewater were extracted by density separation. The size, shape, color, and type of microplastics were analyzed and identified using the integrated microscope and FTIR. The whole experiment was carried out about a month. The results showed that the microplastics removal efficiency of rural WWTP1 was 72.38%, and that of rural WWTP2 was 68.10%, which were lower than that of most urban WWTPs. The microplastics removal efficiency of constructed wetlands in rural WWTP1 was 26.59%, and that in rural WWTP2 was 10.61%. Based on the daily discharge volume and the abundance of microplastics in the effluent of WWTPs, approximately 1.45 ∗ 107 items and 1.73 ∗ 107 items of microplastics were released each day from two rural WWTPs, separately. Fiber was the primary microplastic in both influent and effluent. The polyethylene (PE) and polystyrene (PS) were the main ingredients. The primary source of microplastics in rural WWTPs was inferred as domestic sewage. Microplastics removal efficiencies of rural WWTPs can be improved by regular maintenance, reducing the grid spacing, increasing the hydraulic stay time of biochemical pool, and increasing plant density, changing plant species, or adjusting the size and fill order of matrix in HSSFCWs, which can effectively help to prevent secondary pollution of microplastics from rural WWTPs.


Assuntos
Poluentes Químicos da Água , Purificação da Água , China , Monitoramento Ambiental , Microplásticos , Plásticos , Polietileno , Eliminação de Resíduos Líquidos , Águas Residuárias/análise , Poluentes Químicos da Água/análise , Áreas Alagadas
14.
Toxics ; 9(11)2021 Nov 16.
Artigo em Inglês | MEDLINE | ID: mdl-34822701

RESUMO

Organophosphate esters (OPEs) are widely used as flame retardants and plasticizers. OPEs have been released into various environments (e.g., water, sediments, dust and air, and soil). To investigate the occurrence and distribution of OPEs in various environments in China, this review collects and discusses the published scientific studies in this field. Chlorinated OPEs, as flame retardants, are the predominant OPEs found in the environment. The analysis of data revealed large concentration variations among microenvironments, including inflowing river water (range: 0.69-10.62 µgL-1), sediments (range: 0.0197-0.234 µg/g), dust (range: 8.706-34.872 µg/g), and open recycling sites' soil (range: 0.122-2.1 µg/g). Moreover, OPEs can be detected in the air and biota. We highlight the overall view regarding environmental levels of OPEs in different matrices as a starting point to monitor trends for China. The levels of OPEs in the water, sediment, dust, and air of China are still low. However, dust samples from electronic waste workshop sites were more contaminated. Human activities, pesticides, electronics, furniture, paint, plastics and textiles, and wastewater plants are the dominant sources of OPEs. Human exposure routes to OPEs mainly include dermal contact, dust ingestion, inhalation, and dietary intake. The low level of ecological risk and risk to human health indicated a limited threat from OPEs. Furthermore, current challenges and perspectives for future studies are prospected. A criteria inventory of OPEs reflecting the levels of OPEs contamination association among different microenvironments, emerging OPEs, and potential impact of OPEs on human health, particularly for children are needed in China for better investigation.

15.
Environ Pollut ; 290: 117999, 2021 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-34500397

RESUMO

Microplastics and nanoplastics are distributed in the environments universally. The interrelationship between vascular plants and micro/nanoplastics began to attract attention in recent years. Based on the relevant literatures collected from various databases, this review focuses on two topics: 1) the effect of vascular plants on the fate of micro/nanoplastics; 2) the effects of micro/nanoplastics on vascular plants. The review of the available studies reveals that vascular plants can act as sinks for microplastics and nanoplastics as their surfaces can adsorb these plastics; moreover, nanoplastics can be internalized by plants. Plastics on the surfaces and in the interiors of vascular plants can cause various phytotoxicity effects, including impacts on growth, photosynthesis, and oxidative stress. Furthermore, the results and mechanisms of phytotoxicity effects caused by microplastics or nanoplastics can be very different. However, knowledge gaps still exist in the relationships between micro/nanoplastics and vascular plants based on the analysis of available studies; thus, potential subjects for future studies were proposed, including the fates, analysis methods, influencing factors, mechanisms of phytotoxicity, and further influences of microplastics and nanoplastics in the vascular plant ecosystems. This study presents a review of micro/nanoplastics-vascular plant research and reaches a basis for future research.


Assuntos
Traqueófitas , Poluentes Químicos da Água , Ecossistema , Humanos , Microplásticos , Plásticos/toxicidade , Poluentes Químicos da Água/análise
16.
Sci Total Environ ; 790: 148200, 2021 Oct 10.
Artigo em Inglês | MEDLINE | ID: mdl-34380270

RESUMO

Microplastic pollution has recently gained increasing attention. The accumulation of microplastics in plants has been confirmed in the marine environment. However, the extent of the microplastic retention in freshwater plants is still unknown. In this study, sediment and plant samples from six reed farms in the wetland of East Dongting Lake were collected and analyzed. The abundance of microplastics in the sediment of reed farms varied from 125.7 to 1219.5 items/kg dry weight (dw), with an average of 511.2 ± 295.0 items/kg. Moreover, different levels of microplastic abundance were found in reeds from 0 to 14 items/individual. The abundance of microplastics in sediment samples was moderate compared to that worldwide and higher than that in other regions of Dongting Lake. The microplastic pollution level was significantly higher in the reed vegetation belt than that in other sampling positions. On the basis of the distribution and characteristics of the collected microplastics, lake water and fishery are suggested as important sources of microplastics. Furthermore, the factors influencing microplastic retention in the reeds are discussed. This study, as the first direct evidence demonstrating that freshwater reeds tend to accumulate microplastics, constitutes valuable reference for future research.


Assuntos
Microplásticos , Poluentes Químicos da Água , Monitoramento Ambiental , Sedimentos Geológicos , Lagos , Plásticos , Poluentes Químicos da Água/análise
17.
J Hazard Mater ; 418: 126314, 2021 09 15.
Artigo em Inglês | MEDLINE | ID: mdl-34329029

RESUMO

Poly- and perfluoroalkyl substances (PFASs) are a group of emerging organic contaminants which are persistent to normal physicochemical treatments. The widespread use of PFASs has caused significant environmental issues. The bioaccumulation and distribution of PFASs within plant compartments have revealed great potentials for phytoremediation. In this review, the roles of aquatic plants in the process of PFASs remediation were highlighted. Moreover, there were different underlying mechanisms of PFASs uptake between terrestrial and aquatic plants. On the other hand, a wide range of influencing factors for bioaccumulation and translocation of PFASs within plant compartments are also presented and discussed. In response to exposure of PFASs, corresponding phytotoxic effects has affected the growth and metabolism of plants, which could provide beneficial guides of the phytotoxic tolerance for plant species selection in applications of phytoremediation. Finally, the discussion about whether phytoremediation is a viable option for PFASs removal and further research priorities are suggested.


Assuntos
Fluorocarbonos , Poluentes Químicos da Água , Biodegradação Ambiental , Fluorocarbonos/análise , Fluorocarbonos/toxicidade , Plantas , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/toxicidade
18.
J Hazard Mater ; 415: 125534, 2021 08 05.
Artigo em Inglês | MEDLINE | ID: mdl-33730642

RESUMO

Stabilization is the most important remediation mechanisms for sediment polluted heavy metals. However, little research has been done on the identification of microenvironmental response and internal correlation, as well as synergistic mechanisms during heavy metal remediation. This study aims to investigate the inner response mechanisms of microenvironment after the lead (Pb) are gradually stabilized in sediment. An eco-friendly amendment strategy which firstly used 100% biodegradable sophorolipids (SOP) to modify chlorapatite (ClAP) for the fabrication of SOP@nClAP was applied in this study. The stabilization efficiency of Pb was significantly improved by SOP@nClAP compared with ClAP. Most importantly, the high-throughput sequencing showed that the dominant species in the sediment changed with the stabilization of Pb. The decrease of Proteobacteria and increase of Firmicutes, especially the Sedimentibacter within the phylum Firmicute directly suggested that large amounts of Pb were stabilized. This research is not only devoted to stabilize Pb in sediment by eco-friendly amendment strategy, but also keep a watchful eye on microenvironment response mechanisms during the Pb stabilization in sediment. Therefore, this study lays a foundation for the future application of more heavy metal amendment strategies in the sediment environment and improves the possibility of large-scale site amendment.

19.
J Hazard Mater ; 407: 124399, 2021 04 05.
Artigo em Inglês | MEDLINE | ID: mdl-33191019

RESUMO

Industrial progress has brought us an important polymer material, i.e. plastic. Because of mass production and use, and improper management and disposal, plastic pollution has become one of the most pivotal environmental issues in the world today. However, the current researches on microplastics/nanoplastics are mainly focused on individual aquatic, terrestrial and atmospheric environments, ignoring the fact that the natural environment is a whole. In this regard, the transport of microplastics/nanoplastics among the three environment compartments, including reciprocal contributions and inherent connections, and the impact of microplastics/nanoplastics on organisms living in multiple environments are research problems that we pay special attention to. Furthermore, this paper comprehensively reviews the transport and distribution of microplastics/nanoplastics in individual compartments and the toxicity of organisms, either alone or in combination with other pollutants. The properties of microplastics/nanoplastics, environment condition and the growth habit of organisms are critical to the transport, distribution and toxicity of microplastics/nanoplastics. These knowledge gaps need to be addressed urgently to improve cognition of the degree of plastic pollution and enhance our ability to deal with pollution. Meanwhile, it is hoped that the paper can provide a relatively complete theoretical knowledge system and multiple "leads" for future innovative ideas in this field.


Assuntos
Poluentes Ambientais , Poluentes Químicos da Água , Poluição Ambiental , Microplásticos , Plásticos/toxicidade , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/toxicidade
20.
Chemosphere ; 244: 125486, 2020 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-31812050

RESUMO

There is a lack of research on microplastic pollution in freshwater areas. In this study, microplastic pollution in lakeshore sediments of East Dongting Lake was investigated. The abundance of microplastics ranged from 180 to 693 items/kg in the lakeshore sediment, which was moderate compared with other areas of the world. Fibers, transparent and small sized microplastics accounted for the largest proportion in terms of shape, color and size, respectively. Eight types of microplastics with different polymer compositions were identified by micro-Raman spectroscopy. The study found that the abundance of microplastics in the urban area sediment of Dongting Lake is lower than that of the rural area. The difference in environmental protection measures between urban and rural areas may be the cause of this phenomenon. The results of this study is helpful for understanding the role of human activities in microplastic pollution and provide valuable references for future research.


Assuntos
Monitoramento Ambiental , Microplásticos/análise , Poluentes Químicos da Água/análise , Conservação dos Recursos Naturais , Poluição Ambiental/análise , Sedimentos Geológicos/química , Lagos/química , Plásticos/química
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